1111.1126 (A. Perucchi et al.)

Universal conductivity and the electrodynamics of graphite at high
pressures    [PDF]

A. Perucchi, L. Baldassarre, C. Marini, P. Postorino, F. Bernardini, S. Massidda, S. Lupi

We address the in-plane pressure-dependent electrodynamics of graphite through synchrotron based infrared spectroscopy and ab initio Density Functional Theory calculations. The Drude term remarkably increases upon pressure application, as a consequence of an enhancement of both electron and hole charge densities. This is due to the growth of the band dispersion along the k_z direction between the K and H points of the Brillouin zone. On the other hand, the mid-infrared optical conductivity between 800 and 5000 cm-1 is almost flat, and very weakly pressure dependent, at least up to 7 GPa. This demonstrates a surprising robustness of the graphene-like universal quantum conductance of graphite, even when the interlayer distance is significantly reduced.

View original: http://arxiv.org/abs/1111.1126