Darya M. Sedlovets, Maksim V. Shuvalov, Yury V. Vishnevskiy, Vladimir T. Volkov, Igor I. Khodos, Oleg V. Trofimov, Vitaly I. Korepanov
We propose an experimental approach, by which thin films of copper polyphthalocyanine (CuPPC) can be directly synthesized in a chemical vapor deposition (CVD) set-up at mild temperature (420 {\deg}C). High polymerization degree and high crystallinity of the films was confirmed by TEM, FTIR and UV-VIS studies; the stacking structure of CuPPC layers was determined, inter-layer spacing was estimated from XRD and TEM electron-diffraction. Quantum-chemical study performed providing support for experimental structure determination and yielding information on the electronic structure.
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http://arxiv.org/abs/1303.3694
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