1212.2799 (Miriam Engel et al.)

Reduced Coulomb interaction in organic solar cells by the introduction
of inorganic high-k nanostructured materials    [PDF]

Miriam Engel, David Schaefer, Daniel Erni, Niels Benson, Roland Schmechel

In this article a concept is introduced, which allows for reduced Coulomb interaction in organic solar cells and as such for enhanced power conversion efficiencies. The concept is based on the introduction of electrically insulating, nanostructured high-k materials into the organic matrix, which do not contribute to the charge transport, however, effectively enhance the permittivity of the organic active layer and thereby reduce the Coulomb interaction. Using an analytical model it is demonstrated that even at a distance of 20 nm to the organic / inorganic interface of the nanostructure, the Coulomb interaction can be reduced by more than 15 %. The concept is implemented using P3HT:PCBM solar cells with integrated high-k nanoparticles (strontium titanate). It could be demonstrated that in comparison to a reference cell without integrated nanoparticles, the power conversion efficiencies could be improved by ~20 %.

View original: http://arxiv.org/abs/1212.2799