Monday, June 10, 2013

1306.1812 (John C. Snyder et al.)

Orbital-free Bond Breaking via Machine Learning    [PDF]

John C. Snyder, Matthias Rupp, Katja Hansen, Leo Blooston, Klaus-Robert Müller, Kieron Burke
Machine learning is used to approximate the kinetic energy of one dimensional diatomics as a functional of the electron density. The functional can accurately dissociate a diatomic, and can be systematically improved with training. Highly accurate self-consistent densities and molecular forces are found, indicating the possibility for ab-initio molecular dynamics simulations.
View original: http://arxiv.org/abs/1306.1812

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