Radmir V. Gainutdinov, Andrey A. Shiryaev, Yana Fedortchouk
Surfaces of natural diamonds etched in high-pressure experiments in H2O, CO2 and H2O-NaCl fluids were investigated using Atomic Force Microscopy. Partial dissolution of the crystals produced several types of surface features including the well-known trigons and hillocks and revealed several new types of defects. Besides well-known trigons and dissolution hillocks several new types of defects are observed. The most remarkable ones are assigned to anelastic twins of several types. The observation of abundant microtwins, ordering of hillocks and presence of defects presumably related to knots of branched dislocations suggests importance of post-growth deformation events on formation of diamond microstructure. This work confirms previous reports of ordering of extended defects in some deformed diamonds. In addition, the current work shows that natural diamonds deform not only by dislocation mechanism and slip, but also but mechanical twinning. The dominant mechanism should depend on pressure-temperature-stress conditions during diamond transport from the formation domain to the Earth surface.
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http://arxiv.org/abs/1209.1485
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