1202.3507 (Ernesto Medina et al.)

Chiral molecular films as electron polarizers and polarization
modulators    [PDF]

Ernesto Medina, Floralba López, Mark Ratner, Vladimiro Mujica

Recent experiments on electron scattering through molecular films have shown
that chiral molecules can be efficient sources of polarized electrons even in
the absence of heavy nuclei as source of a strong spin-orbit interaction. We
show that self-assembled monolayers (SAMs) of chiral molecules are strong
electron polarizers due to the high density effect of the monolayers and
explicitly compute the scattering amplitude off a helical molecular model of
carbon atoms. Longitudinal polarization is shown to be the signature of chiral
scattering. For elastic scattering, we find that at least double scattering
events must take place for longitudinal polarization to arise. We predict
energy windows for strong polarization, determined by the energy dependences of
spin-orbit strength and multiple scattering probability. An incoherent
mechanism for polarization amplification is proposed, that increases the
polarization linearly with the number of helix turns, consistent with recent
experiments on DNA SAMs.

View original: http://arxiv.org/abs/1202.3507