1202.3622 (Dijana Zilic et al.)

Study of the local field distribution on a single-molecule magnet-by a
single paramagnetic crystal; a DPPH crystal on the surface of an Mn12-acetate
crystal    [PDF]

Dijana Zilic, Boris Rakvin, Naresh S. Dalal

The local magnetic field distribution on the subsurface of a single-molecule
magnet crystal, SMM, above blocking temperature (T >> Tb) detected for a very
short time interval (~ 10-10 s), has been investigated. Electron Paramagnetic
Resonance (EPR) spectroscopy using a local paramagnetic probe was employed as a
simple alternative detection method. An SMM crystal of
[Mn12O12(CH3COO)16(H2O)4].2CH3COOH.4H2O (Mn12-acetate) and a crystal of 2,2-
diphenyl-1-picrylhydrazyl (DPPH) as the paramagnetic probe were chosen for this
study. The EPR spectra of DPPH deposited on Mn12-acetate show additional
broadening and shifting in the magnetic field in comparison to the spectra of
the DPPH in the absence of the SMM crystal. The additional broadening of the
DPPH linewidth was considered in terms of the two dominant electron spin
interactions (dipolar and exchange) and the local magnetic field distribution
on the crystal surface. The temperature dependence of the linewidth of the
Gaussian distribution of local fields at the SMM surface was extrapolated for
the low temperature interval (70-5 K).

View original: http://arxiv.org/abs/1202.3622