A. Jesche, K. W. Dennis, A. Kreyssig, P. C. Canfield
Single crystals of CaNi2 and CaNi3 were successfully grown out of excess Ca. Both compounds manifest a metallic ground state with enhanced, temperature dependent magnetic susceptibility. The relatively high Stoner factors of Z = 0.79 and Z = 0.87 found for CaNi2 and CaNi3, respectively, reveal their close vicinity to ferromagnetic instabilities. The pronounced field dependence of the magnetic susceptibility of CaNi3 at low temperatures (T < 25 K) suggests strong ferromagnetic fluctuations. A corresponding contribution to the specific heat with a temperature dependence of T^3lnT was also observed.
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http://arxiv.org/abs/1204.6355
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