Chuan Li, Katsuyoshi Komatsu, G. Clave, S. Campidelli, A. Filoramo, S. Gueron, H. Bouchiat
Inducing magnetism in graphene holds great promises, such as new exotic magnetic phases, or the control of exchange interaction via a gate electrode. To reach this goals, graphene has been coated with magnetic or rare earth atoms as well as molecular magnets, with mixed results. Adsorbed magnetic atoms reduced graphene's mobility, with no concurrent magnetic signature. In contrast, the magnetisation reversal of molecular magnets could be detected in a graphene nanoconstriction. In the present work, we use Pt-porphyrins that interact with graphene's delocalised sp2 orbitals. Neutral Pt-porphyrins are non magnetic, but the ionised form carries a magnetic moment of one Bohr magneton. At room temperature we find that the molecules electron-dope the graphene, demonstrating that electron transfer occurs. More surprisingly, the grafted graphene's mobility increases. At low temperature, we show how superconducting contact electrodes can uniquely reveal the magnetic order induced in a mesoscopic, one-micron-long graphene sheet. The unipolar nature of the induced supercurrent, which is enhanced at negative gate voltage but suppressed at positive gate voltage, may be evidence for the long sought after Fermi-level controlled exchange interaction between localised spins and graphene.
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http://arxiv.org/abs/1304.7089
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