Monday, August 20, 2012

1208.3587 (Dianyu Chen et al.)

A recoverable versatile photo-polymerization initiator catalyst    [PDF]

Dianyu Chen, Rongxin Yuan, Soumyajit Roy
A photo-polymerization initiator based on an imidazolium and an oxometalate, viz., (BMIm)2(DMIm) PW12O40 (where, BMIm = 1-butyl-3-methylimizodium, DMIm = 3,3'-Dimethyl-1,1'-Diimidazolium) is reported. It polymerizes several industrially important monomers and is recoverable hence can be reused. The Mn and PDI are controlled and a reaction pathway is proposed.
View original: http://arxiv.org/abs/1208.3587

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